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81.
Lisa K. Whalley Kate L. Furneaux Tom Gravestock Helen M. Atkinson Catherine S. E. Bale Trevor Ingham William J. Bloss Dwayne E. Heard 《Journal of Atmospheric Chemistry》2007,58(1):19-39
A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere.
An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of
the IO A2Π3/2 ← X2Π3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument
was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N2O/CF3I/N2 mixtures with O3 actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration
period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer)
campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured
significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing
the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum
at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF. 相似文献
82.
Hg、As、Sb是土壤和河流沉积物的常规测定项目。本文采用新型三通道原子荧光分析仪,建立了同时测定土壤和河流沉积物中这三种元素的新方法。通过优化仪器工作条件,选择合适的样品处置方法,得到Hg、As、Sb的检出限分别为0.03mg/kg、0.009mg/kg和0.03mg/kg,精密度分别为3.5%、7.8%和5.5%,准确度分别为95%~103%、91%~107%(加标回收率)和±6.4%。与现有测定方法相比,本方法的样品消化完全,实验简便,分析速度和准确度高,能充分满足分析要求。 相似文献
83.
Micro-spectroscopic investigations of highly heterogeneous waste repository materials 总被引:1,自引:0,他引:1
A.M. Scheidegger D. Grolimund C.R. Cheeseman R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59
Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented. 相似文献
84.
Hsueh-Yu Lu 《Environmental Geology》2007,51(6):1029-1041
A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical
compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that
hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical
composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions
economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field.
In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic
conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic
equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers
composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends
to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study. 相似文献
85.
原子荧光光谱分析环境样品中砷锑铋汞易出现的问题及解决方法 总被引:2,自引:0,他引:2
针对原子荧光光谱法测试砷锑铋汞中易出现的仪器空白不稳定、样品制备及仪器污染等问题,总结出相应的解决方法。 相似文献
86.
Depth profiles of fluorescence at several excitation and emission wavelengths were measured along with CTD data during the
cruise So119 of RV Sonne in the Arabian Sea from 12 May to 10 June 1997. In addition to chlorophyll fluorescence from phytoplankton in the near-surface
layer, the profiles in the oxygen minimum region well below the euphotic zone show enhanced red fluorescence. Red fluorescence
intensity is inversely related to the oxygen concentration in intermediate and deep waters. A relationship to characteristic
water masses of the region cannot be found in the data, and this holds also with chemical data such as DOC. Absorbance spectra
of water samples taken in the oxygen minimum zone show an absorption band at 420 nm wavelength with about 50 nm bandwidth,
much weaker than gelbstoff absorbance in the same wavelength range. The absorption band remains stable after sample filtration
with 0.45 μm glass fibre filters. Hence, the size of the absorbing matter is in the range of dissolved molecules or particles
much smaller than 1 μm. Fluorescence spectra of unfiltered samples with 420 nm excitation show a weak emission band at 600
nm and a more pronounced one at 660 nm wavelength. The trailing edge of the 660 nm band falls into the range of chlorophyll
emission, thus giving rise to the observed depth profiles of red fluorescence in the oxygen minimum zone. Red fluorescence
measured on samples remain stable during a few hours after sampling even in the presence of oxygen. It is not detectable after
several weeks of sample storage in the dark and cannot be reproduced even after depletion of dissolved oxygen.
Received: 22 May 2002 / Accepted: 18 February 2003
Responsible Editor: Andreas Oschlies
Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the frame work of
the JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. We are indebted to Mrs. Kirsten Neumann from the Institute of Marine Chemistry and Biogeochemistry of
the University of Hamburg for providing the oxygen data, and to Mr. Nikolai Delling from the same institute for making the
DOC and chlorophyll data available to us. 相似文献
87.
原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰 总被引:1,自引:0,他引:1
通过研究黑龙江省森林沼泽景观区有机水系沉积物(泥炭)、土壤中As,Sb,Bi的测定结果,发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰,提出采用低温(<450℃)灰化处理可完全消除干扰。对比研究还发现,过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题,应专门对其进行评价研究。 相似文献
88.
89.
简述了瑞士ARL 9400型X荧光光谱仪探测器高压部分的故障现象、分析与处理及维修方法,并给出了维修实例。 相似文献
90.
应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。 相似文献